2-Bromo-4-nitrophenol → 4-Amino-2-bromophenol

HRID 2386964Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2386964
[Br:1][C:2]1[CH:7]=[C:6]([N+:8]([O-])=O)[CH:5]=[CH:4][C:3]=1[OH:11].[Cl-].[NH4+]>[Fe].CO>[NH2:8][C:6]1[CH:5]=[CH:4][C:3]([OH:11])=[C:2]([Br:1])[CH:7]=1

Komponenten

5

Edukt 2

HCID 221092-Bromo-4-nitrophenol2×HCID 25517Ammonium Chloride

Produkt 1

HCID 144402654-Amino-2-bromophenol

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23925IronKatalysatorHCID 887MethanolLösungsmittel

Versuchsvorschrift

The target compound was obtained by reducing 2-bromo-4-nitrophenol with iron in a mixed solution of methanol and ammonium chloride aqueous solution. 2-bromo-4-nitrophenol was manufactured by the method described in the literature (J. Org. Chem., Vol. 62, 1997, p. 4504).

Aufarbeitung

  1. customThe target compound was obtained

Quellen und Nachweise

ORD-Eintrag
ord-5a4a848ad6ad4a9bb141bd1e26fb4728
Quelldatensatz
uspto-grants-2012_09
Patentnummer
US08268842B2

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