Epichlorohydrin → HCID 18980716, Verbindung

HRID 2392920Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2392920
[OH:1][CH:2]([CH2:17][N:18]([CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH3:47])[CH2:19][CH:20]([OH:35])[CH2:21][NH:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[CH2:3][NH:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[CH2:48]([CH:50]1[O:52][CH2:51]1)[Cl:49]>C1(C)C(C)=CC=CC=1>[OH:35][CH:20]([CH2:19][N:18]([CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH3:47])[CH2:17][CH:2]([OH:1])[CH2:3][N:4]([CH2:51][CH:50]([OH:52])[CH2:48][Cl:49])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[CH2:21][N:22]([CH2:51][CH:50]([OH:52])[CH2:48][Cl:49])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34]

Komponenten

4

Edukt 2

HCID 7835EpichlorohydrinHCID 18980712HCID 18980712, Verbindung

Produkt 1

HCID 18980716HCID 18980716, VerbindungAusbeute 99,4 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 7237O-XyleneLösungsmittel

Versuchsvorschrift

A reactor was charged with 16.6 g (0.025 mole) of 15,19-dihydroxy-17-dodecyl-13,17,21-triazatritriacontane obtained in Example 1 and 200 g of xylene, and the contents were kept at 50° C. To the contents, 6.9 g (0.075 mole) of epichlorohydrin was added dropwise over one hour and ten minutes, and the resultant mixture was aged for 36 hours. Thereafter, the solvent and unreacted epichlorohydrin were distilled off under reduced pressure at room temperature, thereby obtaining 21.2 g of 15,19-dihydroxy-13,21-bis(3-chloro-2-hydroxypropyl)-17-dodecyl-13,17,21-triazatritriacontane represented by the following formula. ##STR14##

Aufarbeitung

  1. customwere kept at 50° C
  2. distillationThereafter, the solvent and unreacted epichlorohydrin were distilled off under reduced pressure at room temperature

Quellen und Nachweise

ORD-Eintrag
ord-d0af5596bcfc44288aeb2cc9bbadc896
Quelldatensatz
uspto-grants-1998_09
Patentnummer
US05801270

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