4-tert-Butylbenzoyl chloride → N-(4-t-Butylbenzoyl)-4-(2-bromoethyl)benzenesulfonamide

HRID 2392982Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2392982
[Br:1][CH2:2][CH2:3][C:4]1[CH:9]=[CH:8][C:7]([S:10]([NH2:13])(=[O:12])=[O:11])=[CH:6][CH:5]=1.[C:14]([C:18]1[CH:26]=[CH:25][C:21]([C:22](Cl)=[O:23])=[CH:20][CH:19]=1)([CH3:17])([CH3:16])[CH3:15]>C1(C)C(C)=CC=CC=1>[C:14]([C:18]1[CH:19]=[CH:20][C:21]([C:22]([NH:13][S:10]([C:7]2[CH:6]=[CH:5][C:4]([CH2:3][CH2:2][Br:1])=[CH:9][CH:8]=2)(=[O:11])=[O:12])=[O:23])=[CH:25][CH:26]=1)([CH3:17])([CH3:15])[CH3:16]

Komponenten

4

Edukt 2

HCID 743724-tert-Butylbenzoyl chlorideHCID 144850914-(2-Bromoethyl)benzenesulfonamide

Produkt 1

HCID 18977847N-(4-t-Butylbenzoyl)-4-(2-bromoethyl)benzenesulfonamide

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 7237O-XyleneLösungsmittel

Versuchsvorschrift

A mixture of 26.41 g (0.10 mol) of 4-(2-bromoethyl)benzenesulfonamide, 19.67 g (0.10 mol) of 4-t-butylbenzoyl chloride and 160 ml of xylene was heated at reflux for 20 hrs. The hot solution was cooled and the solid which crystallized was collected, recrystallized from isopropanol collected, washed with ligroine and dried.

Aufarbeitung

  1. temperaturewas heated
  2. temperatureat reflux for 20 hrs
  3. temperatureThe hot solution was cooled
  4. customthe solid which crystallized
  5. customwas collected
  6. customrecrystallized from isopropanol
  7. customcollected
  8. washwashed with ligroine
  9. customdried

Quellen und Nachweise

ORD-Eintrag
ord-23c317b380a94066a46fe7c4f084d972
Quelldatensatz
uspto-grants-1998_09
Patentnummer
US05804348

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