Chlorodiphenylmethane → 1-Benzhydrylindole-4-carbaldehyde

Reaktionsgleichung

[NH:1]1[C:9]2[CH:8]=[CH:7][CH:6]=[C:5]([CH:10]=[O:11])[C:4]=2[CH:3]=[CH:2]1.[CH:12](Cl)([C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1)[C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>>[CH:12]([N:1]1[C:9]2[CH:8]=[CH:7][CH:6]=[C:5]([CH:10]=[O:11])[C:4]=2[CH:3]=[CH:2]1)([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1

Komponenten

Edukt 2

HCID 7035Chlorodiphenylmethane

HCID 333703Indole-4-carboxaldehyde

Produkt 1

HCID 189735061-Benzhydrylindole-4-carbaldehyde

Versuchsvorschrift

The same procedures used in Example 1 were repeated except for using 870 mg of indole-4-carbaldehyde and benzhydryl chloride instead of the benzyl bromide used in Example 1 to give 1.14 g of 1-benzhydrylindole-4-carbaldehyde as an orange-colored oily substance. The yield thereof was found to be 61%.

Quellen und Nachweise

ORD-Eintrag: ord-262d019cfc014ce09bff2d005b798632
Quelldatensatz: uspto-grants-1998_09
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US05811439

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