HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
2-Benzylidenebutanoic acid → 2-Benzylbutanoic acid
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 2-Benzylidenebutanoic acid | HCID 235117 | — |
| Edukt | HCID 178418361 | HCID 178418361 | — |
| Katalysator | Palladium | HCID 23938 | — |
| Lösungsmittel | Sodium Hydroxide | HCID 14798 | — |
| Produkt | 2-Benzylbutanoic acid | HCID 21881 | 100% |
Reaktionsschritte
A solution of 35.2 gm (0.2 mol) of α-ethyl cinnamic acid in 450 ml of 3% sodium hydroxide was reduced in a hydrogen atmosphere at 60 psi using 4 gm of 5% palladium on charcoal. After hydrogen uptake had ceased, the reaction mixture was filtered, acidified with hydrochloric acid and extracted with ether. Evaporation gave 36 gm (0.2 mol) of 2-benzyl butanoic acid.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04022814 |
| Quelldatensatz | uspto-grants-1977_05 |
| ORD ID | ord-bae2a6957965486d905a0c1e072beae2 |
| Quellennotiz | uspto-grants-1977_05 |