Tributylamine → 4-(Chloromethyl)benzyltri-n-butylammonium chloride

HRID 2399649

Reaktionsgleichung

Reaktionsgleichung von HRID 2399649
[CH2:1]([N:5]([CH2:10][CH2:11][CH2:12][CH3:13])[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].[Cl:14][CH2:15][C:16]1[CH:21]=[CH:20][C:19]([CH2:22][Cl:23])=[CH:18][CH:17]=1>CO>[Cl-:14].[Cl:23][CH2:22][C:19]1[CH:20]=[CH:21][C:16]([CH2:15][N+:5]([CH2:6][CH2:7][CH2:8][CH3:9])([CH2:10][CH2:11][CH2:12][CH3:13])[CH2:1][CH2:2][CH2:3][CH3:4])=[CH:17][CH:18]=1

Komponenten

4

Edukt 2

HCID 7622TributylamineHCID 12171alpha,alpha'-Dichloro-p-xylene

Produkt 1

HCID 867489774-(Chloromethyl)benzyltri-n-butylammonium chloride

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

A mixture of tri-n-butylamine (6 g, 32.2 mmol) and α,α'-dichloro-p-xylene (8.0 g, 46.0 mmol) in methanol (50 mL) was refluxed for 15 h after which time TLC examination showed completion of the reaction. Methanol was removed under reduced pressure to give an oily residue. The colorless oil was washed several times with toluene and hexane and then dried. The product obtained was used without further purification.

Aufarbeitung

  1. temperaturewas refluxed for 15 h after which time TLC examination
  2. customcompletion of the reaction
  3. customMethanol was removed under reduced pressure
  4. customto give an oily residue
  5. washThe colorless oil was washed several times with toluene and hexane
  6. customdried
  7. customThe product obtained
  8. customwas used without further purification

Quellen und Nachweise

ORD-Eintrag
ord-1b9771ddcf874322a5b72b8cbda070f0
Quelldatensatz
uspto-grants-1995_09
Patentnummer
US05451347

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