2-isopropylidene-1-indanone → HCID 12220946, Verbindung

HRID 2419981Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2419981
[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH:6]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH2:9][CH2:8][NH+:7]=1.[C:16](=[C:19]1[CH2:27][C:26]2[C:21](=[CH:22][CH:23]=[CH:24][CH:25]=2)[C:20]1=O)([CH3:18])[CH3:17]>CO>[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH3:18][C:16]1[C:19]2[CH2:27][C:26]3[C:21](=[CH:22][CH:23]=[CH:24][CH:25]=3)[C:20]=2[N+:7]2[CH2:8][CH2:9][C:10]3[CH:11]=[CH:12][CH:13]=[CH:14][C:15]=3[C:6]=2[CH:17]=1

Komponenten

4

Edukt 2

HCID 15133342-isopropylidene-1-indanoneHCID 20312280HCID 20312280, Verbindung

Produkt 1

HCID 12220946HCID 12220946, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

3,4-Dihydroisoquinolinium perchlorate (2 g) and 2-isopropylidene-indan-1-one (2 g) were heated together at 150° for 2 hours. The reaction mixture was cooled and diluted with methanol. The product was collected by filtration and recrystallized from methanol.

Aufarbeitung

  1. temperatureThe reaction mixture was cooled
  2. filtrationThe product was collected by filtration
  3. customrecrystallized from methanol

Quellen und Nachweise

ORD-Eintrag
ord-cc4c5aaa884f4b46b3e02b6dab696124
Quelldatensatz
uspto-grants-1978_08
Patentnummer
US04108667

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