1,4-Dioxane → 1,1,1,4,4-Pentachloro-1,4-disila-5-hexene

HRID 2420633Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2420633
[Cl:1][Si:2]([Cl:9])([Cl:8])[CH2:3][CH2:4][SiH:5]([Cl:7])[Cl:6].O1CCO[CH2:12][CH2:11]1>>[Cl:1][Si:2]([Cl:9])([Cl:8])[CH2:3][CH2:4][Si:5]([Cl:7])([Cl:6])[CH:11]=[CH2:12]

Komponenten

3

Edukt 2

HCID 312751,4-DioxaneHCID 1019294941,1,1,4,4-Pentachloro-1,4-disilabutane

Produkt 1

HCID 134637291,1,1,4,4-Pentachloro-1,4-disila-5-hexene

Reaktionsbedingungen

Temperatur
0 °C

Versuchsvorschrift

40.00 g (0.152 mol) 1,1,1,4,4-pentachloro-1,4-disilabutane was dissolved in 1000 ml 1,4-dioxane in a 2000 ml vessel. The solution was cooled down to 0° C. and acetylene was bubbled to solution until it was saturated. The solution thus obtained was slowly warmed up to room temperature. 1,4-dioxane was evaporated and obtained crude 1,1,1,4,4-pentachloro-1,4-disila-5-hexene was purified by distillation.

Aufarbeitung

  1. customacetylene was bubbled to solution until it
  2. customThe solution thus obtained
  3. temperaturewas slowly warmed up to room temperature
  4. custom1,4-dioxane was evaporated

Quellen und Nachweise

ORD-Eintrag
ord-8fab220a1ba644d78c28d5c9118a30f3
Quelldatensatz
uspto-grants-2011_06
Patentnummer
US07955660B2

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