Benzyl Alcohol → Benzyl 4-carboxyphenylacetate

HRID 2424224Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2424224
C(C1C=CC(CC(O)=O)=CC=1)=[O:2].C(O)C1C=CC=CC=1.[CH:21]([C:23]1[CH:28]=[CH:27][C:26]([CH2:29][C:30]([O:32][CH2:33][C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)=[O:31])=[CH:25][CH:24]=1)=[O:22]>>[CH2:33]([O:32][C:30]([CH2:29][C:26]1[CH:25]=[CH:24][C:23]([C:21]([OH:2])=[O:22])=[CH:28][CH:27]=1)=[O:31])[C:34]1[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=1

Komponenten

4

Edukt 3

HCID 244Benzyl AlcoholHCID 113441872-(4-formylphenyl)acetic AcidHCID 19966221Benzyl 2-(4-formylphenyl)acetate

Produkt 1

HCID 19966080Benzyl 4-carboxyphenylacetateAusbeute 80,6 %

Versuchsvorschrift

Synthesized from (4-formylphenyl)acetic acid (1 g) and benzyl alcohol (730 mg) according to an analogous synthetic method to Example 806, benzyl (4-formylphenyl)acetate (1.4 g) was used according to an analogous synthetic method to Preparation Example 53 to provide the title compound (1.2 g).

Aufarbeitung

  1. customwas used according to an analogous synthetic method to Preparation Example 53

Quellen und Nachweise

ORD-Eintrag
ord-fdfd933d4e5d4a048180ac237136aadb
Quelldatensatz
uspto-grants-2011_06
Patentnummer
US07960412B2

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