HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
(4-Bromo-3-methylphenyl)methanol → 4-Bromo-3-methylbenzaldehyde
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | (4-Bromo-3-methylphenyl)methanol | HCID 10987288 | — |
| Katalysator | HCID 178418406 | HCID 178418406 | — |
| Lösungsmittel | Dichloromethane | HCID 6344 | — |
| Produkt | 4-Bromo-3-methylbenzaldehyde | HCID 10921521 | 105,2% |
Reaktionsschritte
3.7 g (43 mmol, 10 eq) of manganese dioxide are added to a solution of 900 mg (4.3 mmol, 1 eq) of (4-bromo-3-methylphenyl)methanol in 8 mL of dichloromethane. The reaction mixture is stirred for 12 hours at room temperature. The solid is filtered off and the solvent is evaporated off. 900 mg of 4-bromo-3-methylbenzaldehyde are obtained in oil form and used in the following reaction without further purification.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07863332B2 |
| Quelldatensatz | uspto-grants-2011_01 |
| ORD ID | ord-e8546c71de014eecac7cc34dc7f089c6 |
| Quellennotiz | uspto-grants-2011_01 |