HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
1,2-Dichloroethane → Tropolone
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 1,2-Dichloroethane | HCID 11 | — |
| Edukt | 5-Amino-2-hydroxy-2,4,6-cycloheptatrien-1-one | HCID 23450 | — |
| Edukt | N-Hydroxysulfosuccinimide | HCID 133909 | — |
| Lösungsmittel | Dimethyl Sulfoxide | HCID 679 | — |
| Lösungsmittel | Carbonate Ion | HCID 19660 | — |
| Produkt | Tropolone | HCID 10789 | — |
Reaktionsschritte
To 100E6 carboxylated microspheres (previously activated with sulfo-N-hydroxysuccinimide and EDC) in 0.5 mL of carbonate buffer (pH 9) was added 2 mg of 5-aminotropolone dissolved in 25 μL of dimethyl sulfoxide. The suspension was agitated for 4 hours, and the excess reagent was washed away from the microspheres.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07867774B2 |
| Quelldatensatz | uspto-grants-2011_01 |
| ORD ID | ord-a3f5b91bacba4e389953cdb821e81d21 |
| Quellennotiz | uspto-grants-2011_01 |