HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Oxalyl chloride → Hexahydro-2,5-methano-pentalene-3a-carbonyl chloride
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Oxalyl chloride | HCID 65578 | — |
| Edukt | Hexahydro-2,5-methanopentalene-3a(1H)-carboxylic acid | HCID 2733865 | — |
| Lösungsmittel | Dichloromethane | HCID 6344 | — |
| Produkt | Hexahydro-2,5-methano-pentalene-3a-carbonyl chloride | HCID 13182402 | 99,3% |
Reaktionsschritte
To a solution of commercially available hexahydro-2,5-methano-pentalene-3a-carboxylic acid (10 g, 0.06 mol) in dichloromethane (200 mL) was added oxalyl chloride (8.7 g, 0.066 mol). The mixture was stirred overnight and then concentrated under reduced pressure to afford the title compound as a colorless oil (11 g, 99%). MS (DCI/NH3) m/z 184 (M+H)+.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07875639B2 |
| Quelldatensatz | uspto-grants-2011_01 |
| ORD ID | ord-82faefc782d147d88966d283fa9acab9 |
| Quellennotiz | uspto-grants-2011_01 |