Potassium Nitrate → N-(3-formyl-4-nitrophenyl)acetamide

HRID 256183

Reaktionsgleichung

[N+:1]([O-:4])([O-])=[O:2].[K+].[CH:6]([C:8]1[CH:9]=[C:10]([NH:14][C:15](=[O:17])[CH3:16])[CH:11]=[CH:12][CH:13]=1)=[O:7]>S(=O)(=O)(O)O>[CH:6]([C:8]1[CH:9]=[C:10]([NH:14][C:15](=[O:17])[CH3:16])[CH:11]=[CH:12][C:13]=1[N+:1]([O-:4])=[O:2])=[O:7]

Komponenten

Reaktionsbedingungen

Temperatur: 5 °C

Versuchsvorschrift

A solution of potassium nitrate (6.2 g, 61 mmol) in sulfuric acid (30 mL) was added dropwise to stirred solution of N-(3-formylphenyl)acetamide (10.0 g, 61 mmol) in sulfuric acid (120 mL) maintained at 5° C. After 2 hours, the reaction mixture was poured onto ice water (500 mL) and filtered to give N-(3-formyl-4-nitrophenyl)acetamide (6.2 g, 48%) mp 131°-135° C., used without further purification.

Aufarbeitung

additionthe reaction mixture was poured onto ice water (500 mL)
filtrationfiltered

Quellen und Nachweise

ORD-Eintrag: ord-d972c48809d24f6790d4889bc1c8c1e7
Quelldatensatz: uspto-grants-1987_10
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04701459

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