Pyridine → S-Methylglutathione

HRID 258234

Reaktionsgleichung

Reaktionsgleichung von HRID 258234
[NH2:1][C@@H:2]([CH2:6][CH2:7][C:8]([NH:10][C@H:11]([C:14]([NH:16][CH2:17][C:18]([OH:20])=[O:19])=[O:15])[CH2:12][SH:13])=[O:9])[C:3]([OH:5])=[O:4].N1C=CC=C[CH:22]=1>>[CH3:22][S:13][CH2:12][C@@H:11]([C:14]([NH:16][CH2:17][C:18]([OH:20])=[O:19])=[O:15])[NH:10][C:8](=[O:9])[CH2:7][CH2:6][C@@H:2]([C:3]([OH:5])=[O:4])[NH2:1]

Komponenten

3

Edukt 2

HCID 1049PyridineHCID 124886Glutathione

Produkt 1

HCID 115260S-Methylglutathione

Versuchsvorschrift

When glutathione was complexed with Cr(II), no measurable oxidation of the Cr(II) was observed until the appropriate pyridine derivative was added to the complex mixture. At this time, the 280 nm-340 nm charge transfer peak also appeared. At no time were the 450 nm and 585 nm peaks attributable to Cr--S observed. Replacing glutathione with S-methylglutathione gave identical results.

Aufarbeitung

  1. additionwas added to the complex mixture
  2. additionAt this time, the 280 nm-340 nm charge transfer peak

Quellen und Nachweise

ORD-Eintrag
ord-0f98d2e79fb94967b51a506e029bc6aa
Quelldatensatz
uspto-grants-1993_11
Patentnummer
US05266560

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