2-Butoxyethanol → 2-Butoxyethyl Levulinate

HRID 25892

Reaktionsgleichung

Reaktionsgleichung von HRID 25892
[CH2:1]([O:5][CH2:6][CH2:7]O)[CH2:2][CH2:3][CH3:4].[C:9]([OH:16])(=[O:15])[CH2:10][CH2:11][C:12]([CH3:14])=[O:13].CCCCCCCC(O[Sn](OC(CCCCCCC)=O)(CCCC)CCCC)=O>C1(C)C(C)=CC=CC=1>[C:9]([O:16][CH2:7][CH2:6][O:5][CH2:1][CH2:2][CH2:3][CH3:4])(=[O:15])[CH2:10][CH2:11][C:12]([CH3:14])=[O:13]

Komponenten

5

Edukt 3

HCID 81332-ButoxyethanolHCID 11579Levulinic AcidHCID 16683953Dibutyltin dioctanoate

Produkt 1

HCID 213256432-Butoxyethyl Levulinate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 7237O-XyleneLösungsmittel

Versuchsvorschrift

2 -Butoxyethanol (Butyl Cellosolve) 354g (3 mol), 232g (2 mol) levulinic acid and 1.5g dibutyl tin dioctoate were heated with a xylene azeotrope for 24 hours 151°-177° to AN 2.3 while collecting 42g water. Product was washed with sat. NaHCO3 and water, dried with anhy. MgSO4 and distilled. Ester product was collected in fr 2 and 3 120°-131° 1 mm. Yield was 349g, 81%, 96% ester product by gc.

Aufarbeitung

  1. customwhile collecting 42g water
  2. washProduct was washed with sat. NaHCO3 and water
  3. customdried with anhy
  4. distillationMgSO4 and distilled
  5. customEster product was collected in fr 2 and 3 120°-131° 1 mm
  6. customYield

Quellen und Nachweise

ORD-Eintrag
ord-abc3c1bef80649e3acc4e6b3f41db6cd
Quelldatensatz
uspto-grants-1979_04
Patentnummer
US04147686

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