Hexamethylphosphorous triamide → HCID 23414757, Verbindung

HRID 259490Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 259490
[NH:1]1[CH2:14][CH2:13][CH2:12][NH:11][CH2:10][CH2:9][CH2:8][NH:7][CH2:6][CH2:5][NH:4][CH2:3][CH2:2]1.CN(C)[P:17](N(C)C)N(C)C>>[N:1]12[P:17]3[N:11]([CH2:10][CH2:9][CH2:8][N:7]3[CH2:6][CH2:5][NH:4][CH2:3][CH2:2]1)[CH2:12][CH2:13][CH2:14]2

Komponenten

3

Edukt 2

HCID 15355Hexamethylphosphorous triamideHCID 63974791,4,7,11-Tetraazacyclotetradecane

Produkt 1

HCID 23414757HCID 23414757, Verbindung

Versuchsvorschrift

A stirred mixture of 6.00 g (30 mmol) of 1,4,7,11-tetraazacyclotetradecane and 4.90 g of hexamethylphosphorous triamide is heated under nitrogen for 3 hr at 120° and then distilled in a short-path apparatus to give 5.50 g (80%) of clear, colorless liquid 1,5,9,12-tetraaza-15-phosphatricyclo[7.5.1.05,15 ]pentadecane, bp 106°-110° (0.30 mm), which solidifies on storing below 0°.

Aufarbeitung

  1. temperatureis heated under nitrogen for 3 hr at 120°
  2. distillationdistilled in a short-path apparatus

Quellen und Nachweise

ORD-Eintrag
ord-d4afc4dfb59247bfba75ef724dd5e9a3
Quelldatensatz
uspto-grants-1977_07
Patentnummer
US04038312

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