1-Benzhydrylamino-2-methylpropanephosphonous acid → 1-Amino-p-chlorophenylmethanephosphonous acid

Reaktionsgleichung

C([NH:14][C:15]1([CH:24]=[CH:23][C:22]([Cl:25])=[CH:21][CH2:20]1)[CH2:16][P:17]([OH:19])[OH:18])(C1C=CC=CC=1)C1C=CC=CC=1.C(NC(P(O)O)C(C)C)(C1C=CC=CC=1)C1C=CC=CC=1>>[NH2:14][C:15]1([CH2:16][P:17]([OH:19])[OH:18])[CH:20]=[CH:21][C:22]([Cl:25])=[CH:23][CH2:24]1

Komponenten

Edukt 2

HCID 213258821-Benzhydrylamino-2-methylpropanephosphonous acid

HCID 867364401-Benzhydrylamino-p-chlorobenzylphosphonous acid

Produkt 1

HCID 867364391-Amino-p-chlorophenylmethanephosphonous acid

Versuchsvorschrift

The procedure described in Example 1C was repeated using DL-1-benzhydrylamino-p-chlorobenzylphosphonous acid as starting material instead of DL-1-benzhydrylamino-2-methylpropanephosphonous acid to give DL-1-amino-p-chlorophenylmethanephosphonous acid of melting point 228°-230° (dec.).

Quellen und Nachweise

ORD-Eintrag: ord-774415ecd1ab4e1aba804245b5e5c920
Quelldatensatz: uspto-grants-1979_04
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04147780

Notizen zur Reaktion

Wird geladen…