3-Heptanoylindole → (E)-4-methoxybenzyl 4-[3-(2-decenoyl)-1-indolyl]butyrate
Reaktionsgleichung
[C:1]([C:12]1[C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[NH:14][CH:13]=1)(=[O:11])/[CH:2]=[CH:3]/[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].C(C1C2C(=CC=CC=2)NC=1)(=O)CCCCCC.Br[CH2:39][CH2:40][CH2:41][C:42]([O:44][CH2:45][C:46]1[CH:51]=[CH:50][C:49]([O:52][CH3:53])=[CH:48][CH:47]=1)=[O:43]>>[C:1]([C:12]1[C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[N:14]([CH2:39][CH2:40][CH2:41][C:42]([O:44][CH2:45][C:46]2[CH:51]=[CH:50][C:49]([O:52][CH3:53])=[CH:48][CH:47]=2)=[O:43])[CH:13]=1)(=[O:11])/[CH:2]=[CH:3]/[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]Komponenten
4
Versuchsvorschrift
The procedure of Ex. 1 was repeated except that (E)-3-(2-decenoyl)indole obtained in Pre. Ex. 23 was used in place of 3-heptanoylindole, and 4-methoxybenzyl 4-bromobutyrate was used in place of 4-bromobutyrate to give (E)-4-methoxybenzyl 4-[3-(2-decenoyl)-1-indolyl]butyrate.