Dimethyldithiocarbamic acid, dimethylamine → p-Isopropyl-alpha-(nitromethyl)benzyl dimethyldithiocarbamate
Reaktionsgleichung
[CH:1]([C:4]1[CH:14]=[CH:13][C:7]([CH:8]=[CH:9][N+:10]([O-:12])=[O:11])=[CH:6][CH:5]=1)([CH3:3])[CH3:2].[CH3:15][N:16]([CH3:20])[C:17](=[S:19])[S-:18].C[NH2+]C>C(=S)=S>[CH3:15][N:16]([CH3:20])[C:17](=[S:18])[S:19][CH:8]([CH2:9][N+:10]([O-:12])=[O:11])[C:7]1[CH:13]=[CH:14][C:4]([CH:1]([CH3:3])[CH3:2])=[CH:5][CH:6]=1Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
As in Example 17, reaction of p-isopropyl-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave p-isopropyl-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 119° C.-120° C. after recrystallization without heating from acetone-methanol solution.