Dimethyldithiocarbamic acid, dimethylamine → p-Methoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate
Reaktionsgleichung
[CH3:1][O:2][C:3]1[CH:13]=[CH:12][C:6]([CH:7]=[CH:8][N+:9]([O-:11])=[O:10])=[CH:5][CH:4]=1.[CH3:14][N:15]([CH3:19])[C:16](=[S:18])[S-:17].C[NH2+]C>C(=S)=S>[CH3:14][N:15]([CH3:19])[C:16](=[S:17])[S:18][CH:7]([CH2:8][N+:9]([O-:11])=[O:10])[C:6]1[CH:5]=[CH:4][C:3]([O:2][CH3:1])=[CH:13][CH:12]=1Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
As in Example 17, reaction of p-methoxy-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave p-methoxy-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 86° C.-89° C. when recrystallized without heating from acetone-ethanol solution.