Htris → 2,2-Diethyl-5-indanacetic acid

HRID 261536

Reaktionsgleichung

Reaktionsgleichung von HRID 261536
C[O:2][C:3](=[O:19])[C:4](=O)[C:5]1[CH:6]=[C:7]2[C:11](=[CH:12][CH:13]=1)[CH2:10][C:9]([CH2:16][CH3:17])([CH2:14][CH3:15])[CH2:8]2.OCC([NH3+])(CO)CO>>[CH2:16]([C:9]1([CH2:14][CH3:15])[CH2:8][C:7]2[C:11](=[CH:12][CH:13]=[C:5]([CH2:4][C:3]([OH:19])=[O:2])[CH:6]=2)[CH2:10]1)[CH3:17]

Komponenten

3

Edukt 2

HCID 3777159HtrisHCID 536366772,2-Diethyl-alpha-oxo-5-indanacetic acid methyl ester

Produkt 1

HCID 203944522,2-Diethyl-5-indanacetic acid

Versuchsvorschrift

2,2-diethyl-α-oxo-5-indanacetic acid methyl ester is reduced in a manner analogous to that described in Example 4. The (1,3-dihydroxy-2-hydroxymethyl-2-propyl)ammonium salt of the title compound has an M.P. of 116°-119°.

Quellen und Nachweise

ORD-Eintrag
ord-7bc7bad2cce748b48dd617b74764efbb
Quelldatensatz
uspto-grants-1979_08
Patentnummer
US04166131

Verknüpfte Notizen

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