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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 262024Erstellt: 27. Oktober 2026

Formaldehyde → 2-Methyl-1,4-butanediol

https://huagongshe.com/reaction/262024

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktFormaldehydeHCID 712—
EduktButanediolHCID 165788—
EduktBut-2-yne-1,1-diolHCID 18778928—
Produkt2-Methyl-1,4-butanediolHCID 18053—
ProduktButanediolHCID 165788—

Reaktionsschritte

As described in detail in copending application Ser. No. 924,212, filed July 12, 1978, (FDN-1113), the catalyst of the invention will produce high quality butanediol by a process involving a two-stage catalytic hydrogenation of a butynediol solution containing formaldehyde. During the first stage of the process, or low pressure, low temperature stage, a butanediol product having a much lower carbonyl number is obtained. The carbonyl number is the conventional measure of the undesired aldehyde and acetal content including residual formaldehyde. In the second or finishing stage, which is carried out at higher pressures and/or temperatures than the first stage, much less 2-methyl-1,4-butanediol byproduct (methylbutanediol) is produced concurrently with butanediol.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS04153578
Quelldatensatzuspto-grants-1979_05
ORD IDord-33a900d217334a2288501591534d1cdd
Quellennotizuspto-grants-1979_05