HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
1,2-Benzenedicarbonitrile, 4-nitro- → 4-Phenoxyphthalonitrile
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 1,2-Benzenedicarbonitrile, 4-nitro- | HCID 97443 | — |
| Edukt | Phenolate Sodium | HCID 4445035 | — |
| Lösungsmittel | Dimethylformamide | HCID 6228 | — |
| Produkt | 4-Phenoxyphthalonitrile | HCID 371800 | 49% |
Reaktionsschritte
The procedure of Example 35 was followed except that 1,2-dicyano-4-nitrobenzene (1.0 part) was used in place of the 1,2-dicyano-3-nitrobenzene, 1.0 parts instead of 2.79 parts of sodium phenoxide and 20 parts instead of 50 parts of dimethylformamide were used. 1,2-Dicyano-4-phenoxybenzene (0.6 parts, 49%) was obtained as a white solid, m.pt.98°-100° C.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05730759 |
| Quelldatensatz | uspto-grants-1998_03 |
| ORD ID | ord-690d3f8480e44e9f98c5d08baf524723 |
| Quellennotiz | uspto-grants-1998_03 |