HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Water → Gamma-Butyrolactone
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Water | HCID 962 | — |
| Edukt | Tetrahydrofuran | HCID 8028 | — |
| Edukt | 2,5-Dihydrofuran | HCID 15570 | — |
| Katalysator | Rhenium | HCID 23947 | — |
| Lösungsmittel | 1-Butanol | HCID 263 | — |
| Produkt | Gamma-Butyrolactone | HCID 7302 | — |
| Produkt | Furan | HCID 8029 | — |
Reaktionsschritte
In a manner similar to that described in Example 5 14 mL/h of 2,5-dihydrofuran and 24 mL/h of water were passed over the rhenium-on-activated charcoal catalyst at 220° C. At quantitative conversion, γ-butyrolactone was formed with a selectivity of 87% (furan: 2.5%; tetrahydrofuran: 9%; n-butanol: 1%; remainder: various non-analyzed low-boiling fractions).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05646307 |
| Quelldatensatz | uspto-grants-1997_07 |
| ORD ID | ord-7d76b87c4a6741e8bd563914536cd62a |
| Quellennotiz | uspto-grants-1997_07 |