Reaktionsgleichung
[O:1]1[CH2:5][CH:4]=[CH:3][CH2:2]1.O.[O:7]1[CH2:11][CH2:10][CH2:9][CH2:8]1>[Re].C(O)CCC>[C:5]1(=[O:7])[O:1][CH2:2][CH2:3][CH2:4]1.[O:7]1[CH:11]=[CH:10][CH:9]=[CH:8]1Komponenten
7
Edukt 3
Produkt 2
Reagenzien, Katalysatoren, Lösungsmittel 2
Versuchsvorschrift
In a manner similar to that described in Example 5 14 mL/h of 2,5-dihydrofuran and 24 mL/h of water were passed over the rhenium-on-activated charcoal catalyst at 220° C. At quantitative conversion, γ-butyrolactone was formed with a selectivity of 87% (furan: 2.5%; tetrahydrofuran: 9%; n-butanol: 1%; remainder: various non-analyzed low-boiling fractions).
Quellen und Nachweise
- ORD-Eintrag
- ord-7d76b87c4a6741e8bd563914536cd62a
- Quelldatensatz
- uspto-grants-1997_07
- Patentnummer
- US05646307
Verknüpfte Notizen
Wird geladen…