m-Chloroperbenzoic acid → 11-methylene-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine

HRID 26521

Reaktionsgleichung

Reaktionsgleichung von HRID 26521
[CH2:1]=[C:2]1[C:8]2[CH:9]=[CH:10][CH:11]=[CH:12][C:7]=2[CH:6]=[CH:5][N:4]2[C:13]([S:16][CH3:17])=[N:14][N:15]=[C:3]12.ClC1C=CC=C(C(OO)=[O:26])C=1>>[CH2:1]=[C:2]1[C:8]2[CH:9]=[CH:10][CH:11]=[CH:12][C:7]=2[CH:6]=[CH:5][N:4]2[C:13]([S:16]([CH3:17])=[O:26])=[N:14][N:15]=[C:3]12

Komponenten

3

Edukt 2

HCID 70297m-Chloroperbenzoic acidHCID 2132340911-methylene-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine

Produkt 1

HCID 2132336711-methylene-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine

Versuchsvorschrift

By a procedure similar to that of Example 17, the reaction of 11-methylene-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine with m-chloroperbenzoic acid gave 11-methylene-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine as crystals. Recrystallization from ethyl acetate yielded colorless prisms, m.p. 140°-142° C.

Quellen und Nachweise

ORD-Eintrag
ord-9ffaacf5506e43fda0f716845647efb3
Quelldatensatz
uspto-grants-1979_04
Patentnummer
US04150139

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