Hydroquinone → Hydroquinone sulphur hexafluoride
Reaktionsgleichung
[C:1]1([CH:8]=[CH:7][C:5]([OH:6])=[CH:4][CH:3]=1)[OH:2].[S:9]([F:15])([F:14])([F:13])([F:12])([F:11])[F:10]>C(O)CC>[C:1]1([CH:8]=[CH:7][C:5]([OH:6])=[CH:4][CH:3]=1)[OH:2].[S:9]([F:15])([F:14])([F:13])([F:12])([F:11])[F:10]Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
Hydroquinone (30 g) was dissolved in n-propanol (70 ml) at 70° C. The hot solution was introduced into the high pressure autoclave. The solution was subjected to compressed sulphur hexafluoride of 300 bar. The high pressure autoclave was kept for 2 h at 80° C. The solution was then cooled down to room temperature within 5 days. The crystals were filtered off and washed 4 times with cold n-propanol (5 ml). The crystals were then dried in the drying cabinet at 70° C.