HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Imidazole → N-(1-Hexylheptyl)perylene-3,4-dicarboximide
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Imidazole | HCID 795 | — |
| Edukt | Water | HCID 962 | — |
| Edukt | 3,4,9,10-Perylenetetracarboxylic dianhydride | HCID 67191 | — |
| Edukt | Tridecan-7-amine | HCID 574991 | — |
| Edukt | N-(2,5-Di-t-butylphenyl)perylene-3,4-dicarboximide | HCID 11081772 | — |
| Katalysator | Zinc acetate (USP) | HCID 2724192 | — |
| Produkt | N-(1-Hexylheptyl)perylene-3,4-dicarboximide | HCID 11443487 | — |
Reaktionsschritte
1.2 g (3.1 mmol) of perylene-3,4,9, 10-tetracarboxylic dianhydride, 6.2 g of imidazole, 470 mg (2.36 mmol) of 7-aminotridecane (prepared according to J. Prakt. Chem. 1980, 322, 261), 150 mg (0.68 mmol) of zinc acetate dihydrate and 3.0 ml (170 mmol) of water are heated in an autoclave (100 ml) at 190° C. for 24 h. Workup is analogous to that used in the preparation of 2b. Yield 1.25 g (27%).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05650513 |
| Quelldatensatz | uspto-grants-1997_07 |
| ORD ID | ord-67282756a1ef482bb6fc7c4ab8f27489 |
| Quellennotiz | uspto-grants-1997_07 |