Sodium Azide → HCID 57440193, Verbindung

HRID 269618Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 269618
CS(O[CH2:6][C@@H:7]([NH:18][C:19]([O:21][C:22]([CH3:25])([CH3:24])[CH3:23])=[O:20])[CH2:8][CH2:9][NH:10][C:11]([O:13][C:14]([CH3:17])([CH3:16])[CH3:15])=[O:12])(=O)=O.[N-:26]=[N+:27]=[N-:28].[Na+]>CN(C)C=O>[C:14]([O:13][C:11](=[O:12])[NH:10][CH2:9][CH2:8][C@H:7]([NH:18][C:19]([O:21][C:22]([CH3:25])([CH3:24])[CH3:23])=[O:20])[CH2:6][N:26]=[N+:27]=[N-:28])([CH3:17])([CH3:16])[CH3:15]

Komponenten

4

Edukt 2

HCID 33557Sodium AzideHCID 86601681(2S)-2,4-Bis[(tert-butoxycarbonyl)amino]butyl methanesulphonate

Produkt 1

HCID 57440193HCID 57440193, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6228DimethylformamideLösungsmittel

Versuchsvorschrift

Preparation takes place in analogy to Example 85A from 200 mg (0.52 mmol) of (2S)-2,4-bis[(tert-butoxycarbonyl)amino]butyl methanesulfonate (Example 90A) in 15 ml of dimethylformamide with 34 mg (0.52 mmol) of sodium azide. The product is reacted without further purification.

Aufarbeitung

  1. customPreparation
  2. customThe product is reacted without further purification

Quellen und Nachweise

ORD-Eintrag
ord-ed6e1752664143da84ba51e770eab8e0
Quelldatensatz
uspto-grants-2008_11
Patentnummer
US07446102B2

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