HCID 22314184, Verbindung → HCID 22314057, Verbindung
Reaktionsgleichung
[F:1][C:2]([F:27])([F:26])[C:3]1[CH:8]=[CH:7][C:6]([C:9]2[C:13]3[CH:14]=[CH:15][C:16](OS(C(F)(F)F)(=O)=O)=[CH:17][C:12]=3[S:11][N:10]=2)=[CH:5][CH:4]=1.[CH3:28][O:29][CH2:30][CH2:31][N:32]([CH3:37])[CH:33]([CH3:36])[C:34]#[CH:35]>>[CH3:28][O:29][CH2:30][CH2:31][N:32]([CH3:37])[CH:33]([CH3:36])[C:34]#[C:35][C:16]1[CH:15]=[CH:14][C:13]2[C:9]([C:6]3[CH:7]=[CH:8][C:3]([C:2]([F:1])([F:27])[F:26])=[CH:4][CH:5]=3)=[N:10][S:11][C:12]=2[CH:17]=1Komponenten
3
Versuchsvorschrift
In analogy to example 14.1, Trifluoro-methanesulfonic acid 3-(4-trifluoromethyl-phenyl)-benzo[d]isothiazol-6-yl ester and (2-Methoxy-ethyl)-methyl-(1-methyl-prop-2-ynyl)-amine were converted to yield (2-Methoxy-ethyl)-methyl-{1-methyl-3-[3-(4-trifluoromethyl-phenyl)-benzo[d]isothiazol-6-yl]-prop-2-ynyl}-amine as brown oil, MS: 419 (MH+).
Quellen und Nachweise
- ORD-Eintrag
- ord-5487ed73a7ee42beba608da9ca4924d0
- Quelldatensatz
- uspto-grants-2008_11