HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Benzoyl chloride → (3-Tert-butyl-4-hydroxyphenyl) benzoate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Benzoyl chloride | HCID 7412 | — |
| Edukt | Tert-Butylhydroquinone | HCID 16043 | — |
| Lösungsmittel | Pyridine | HCID 1049 | — |
| Produkt | (3-Tert-butyl-4-hydroxyphenyl) benzoate | HCID 836814 | — |
Reaktionsschritte
Using 6.65 g of 2-tert-butyl-1,4-dihydroxybenzene, 4.6 ml of benzoyl chloride and 200 ml of pyridine, reaction and workup carried out as in Reference Example gave 9.35 g of 4-benzoyloxy-2-tert-butylphenol as white crystals, m.p. 120-121° C. Using. 9.35 g of the white crystals, 1,47 g of sodium hydride, 6.27 g of benzyl bromide and 40 ml of DMF, reaction and workup carried out as in Example 12 gave 6.07 g of yellow oil.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06358515B2 |
| Quelldatensatz | uspto-grants-2002_03 |
| ORD ID | ord-195d0e7013504a89bdc9616bbea8d83a |
| Quellennotiz | uspto-grants-2002_03 |