Dimethylformamide → N,N,N,2,2-Pentamethylpropan-1-aminium iodide

Reaktionsgleichung

[CH2:1](N)[C:2](C)([CH3:4])[CH3:3].[CH2:7](N(CCCC)CCCC)CCC.C[I:21].[CH3:22][N:23]([CH:25]=O)[CH3:24]>>[I-:21].[CH3:22][N+:23]([CH2:25][C:2]([CH3:4])([CH3:3])[CH3:1])([CH3:7])[CH3:24]

Komponenten

Edukt 4

HCID 6228Dimethylformamide

HCID 6328Methyl iodide

HCID 7622Tributylamine

HCID 79882Neopentylamine

Produkt 1

HCID 13652289N,N,N,2,2-Pentamethylpropan-1-aminium iodide

Versuchsvorschrift

11.51 Grams of neopentylamine (Aldrich), 48.7 grams of tributyl amine and 100 ml of DMF were mixed and cooled. 56 Grams of methyl iodide (Aldrich) were added dropwise and the reaction was carried out and worked up as in Example 1.

Aufarbeitung

temperaturecooled

Quellen und Nachweise

ORD-Eintrag: ord-c51cb8b2898444f0a0cd172d02f82682
Quelldatensatz: uspto-grants-1986_05
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04589977

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