Bicarbonate Ion → tert-Butyl 1-vinyl-2-(tert-butyldimethylsilyloxy)-8-azaspiro[4.5]decane-8-carboxylate
Reaktionsgleichung
[C:26]([CH3:27])([CH3:28])([CH3:29])[Si:30]([CH3:31])([CH3:32])[Cl:33].[C:39](=[O:40])([OH:41])[O-:42].[CH:1](=[CH2:2])[CH:3]1[CH:4]([OH:20])[CH2:5][CH2:6][C:7]12[CH2:8][CH2:9][N:10]([C:13](=[O:14])[O:15][C:16]([CH3:17])([CH3:18])[CH3:19])[CH2:11][CH2:12]2.[Na+:43].[O:34]=[CH:35][N:36]([CH3:37])[CH3:38].[nH:21]1[cH:22][cH:23][n:24][cH:25]1>>[CH:1](=[CH2:2])[CH:3]1[CH:4]([O:20][Si:30]([C:26]([CH3:27])([CH3:28])[CH3:29])([CH3:31])[CH3:32])[CH2:5][CH2:6][C:7]12[CH2:8][CH2:9][N:10]([C:13](=[O:14])[O:15][C:16]([CH3:17])([CH3:18])[CH3:19])[CH2:11][CH2:12]2
