HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 2979Erstellt: 23. Oktober 2026
Allyltributylstannane → n-Trimethylsilylethoxymethyl-5-(3'-allyl-4'-methylphenyl)tetrazole
https://huagongshe.com/de/reaction/2979
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Allyltributylstannane | HCID 90628 | — |
| Edukt | 2-Chloromethyl 2-(trimethylsilyl)ethyl ether | HCID 2724271 | — |
| Edukt | 5-(3-Bromo-4-methylphenyl)-2H-tetrazole | HCID 178418249 | — |
| Lösungsmittel | Dimethylformamide | HCID 6228 | — |
| Produkt | n-Trimethylsilylethoxymethyl-5-(3'-allyl-4'-methylphenyl)tetrazole | HCID 69840625 | — |
Reaktionsschritte
A solution of 1.0 mmol of this tetrazole, 2.0 mmol of SEMCl in 10 mL DMF was stirred for 1 h. 2.0 mmol of allyltributyltin and 0.1 mmol of Pd(Ph3)4 was added and heated at 70° C. for 14 h. Chromatography provided N-trimethylsilylethoxymethyl-5-(3'-allyl-4'-methylphenyl)tetrazole.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | US05731432 |
|---|
| Quelldatensatz | uspto-grants-1998_03 |
|---|
| ORD ID | ord-23c1255e56f24480bb48d53be97ec0f6 |
|---|
| Quellennotiz | uspto-grants-1998_03 |
|---|
