HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Thiophosgene → HCID 178440816, Verbindung
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Thiophosgene | HCID 10040 | — |
| Edukt | 3-tert-Butylaniline | HCID 79334 | — |
| Edukt | Sodium Bicarbonate | HCID 516892 | — |
| Lösungsmittel | Acetone | HCID 180 | — |
| Produkt | HCID 178440816 | HCID 178440816 | — |
Reaktionsschritte
To 3-(tert-butyl)phenylamine in acetone at 0° C. was added sodium bicarbonate (2 eq) and thiophosgene (2 eq). The mixture was brought to ambient temperature and concentrated and partitioned between ethyl acetate and water. The organic layer was dried with sodium bicarbonate and sodium sulfate and concentrated to yield 3-(tert-butyl)benzenisothiocyanate. MS: MH+=192.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07423150B2 |
| Quelldatensatz | uspto-grants-2008_09 |
| ORD ID | ord-5c2f9b6dcb724652b0a751510608c005 |
| Quellennotiz | uspto-grants-2008_09 |