Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Ethanol | HCID 702 | — |
| Edukt | Sodium Carbonate | HCID 10340 | — |
| Edukt | (2-Nitrophenyl)boronic acid | HCID 2773548 | — |
| Edukt | 4,4-Dimethylcyclohex-1-ene-1-triflate | HCID 13411668 | — |
| Katalysator | HCID 178418397 | HCID 178418397 | — |
| Lösungsmittel | Toluene | HCID 1140 | — |
| Produkt | 1-(4,4-Dimethylcyclohex-1-enyl)-2-nitrobenzene | HCID 23142003 | — |
Reaktionsschritte
To a solution of 2-nitrophenylboronic acid (14.2 g, 85.19 mmol) in toluene (250 mL)-ethanol(125 mL) were added trifluoromethanesulfonic acid 4,4-dimethylcyclohex-1-enyl ester (20 g, 77.44 mmol) prepared in Example (1a), tetrakis(triphenylphosphine)palladium(0) (4.5 g, 3.87 mmol) and 2N aqueous sodium carbonate (128 mL, 256 mmol). The mixture was stirred at an external temperature of 100° C. for 1 hour and 45 minutes under a nitrogen atmosphere.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | US07425554B2 |
|---|
| Quelldatensatz | uspto-grants-2008_09 |
|---|
| ORD ID | ord-6e5393eb89fa4a778b152028f21849f0 |
|---|
| Quellennotiz | uspto-grants-2008_09 |
|---|
