Reaktionsgleichung
[CH3:1][C:2]([C-:4]1[CH:8]=[CH:7][CH:6]=[CH:5]1)=O.[CH-:9]1[CH:13]=[CH:12][CH:11]=[CH:10]1.[Fe+2:14].C(Br)C=C.[I-].[I-].[Sm+2]>>[C-:9]1([C:5]([CH3:6])=[CH:4][CH:2]=[CH2:1])[CH:13]=[CH:12][CH:11]=[CH:10]1.[CH-:4]1[CH:8]=[CH:7][CH:6]=[CH:5]1.[Fe+2:14]Komponenten
4
Versuchsvorschrift
According to the step flow described in Example 1, about 274 mg (1.20 mmole) of ferrocenyl methyl ketone react with 242 mg (2.0 mmole) of allyl bromide and 1.77 mmole of samarium diiodide in a temperature range of about 0° C. to room temperature to produce an oil-type 1-Ferrocenyl-1-methyl-1,3-butadiene (3b) with a weight of about 302 mg (1.19 mmole) and a yield of about 99%.
Quellen und Nachweise
- ORD-Eintrag
- ord-d2cc93ecc2254f4f940d9c3d542781d0
- Quelldatensatz
- uspto-grants-2001_04
- Patentnummer
- US06211392B1
Verknüpfte Notizen
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