HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Triphenylphosphine → 3-Amino-1-(diphenylmethyl)azetidine
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Triphenylphosphine | HCID 11776 | — |
| Edukt | 3-Azido-1-benzhydrylazetidine | HCID 15512652 | — |
| Lösungsmittel | Water | HCID 962 | — |
| Produkt | 3-Amino-1-(diphenylmethyl)azetidine | HCID 5744546 | — |
Reaktionsschritte
A solution of 10 (5.7 g, 21.6 mmol), triphenylphosphine (11.3 g, 43 mmol) and water (5 ml) was heated to reflux for 24 hours. After cooling to room temperature the solvent was removed in vacuo and the residue purified by chromatography on silica gel (90:9:1 CHCl3:MeOH:NH4OH).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06214832B1 |
| Quelldatensatz | uspto-grants-2001_04 |
| ORD ID | ord-f60b66a271f9493a9e18eb43c1e0e25d |
| Quellennotiz | uspto-grants-2001_04 |