HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
1-Phenylethanol → 1-Phenylethanol, (S)-
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 1-Phenylethanol | HCID 7409 | — |
| Edukt | Acetophenone | HCID 7410 | — |
| Edukt | 1-Phenylethanol, (R)- | HCID 637516 | — |
| Produkt | 1-Phenylethanol, (S)- | HCID 443135 | 61% |
Reaktionsschritte
As shown here, the biochemical conversion reaction of immobilized green pea protein for the substrate (±)-1-phenylethanol (201 mg) requires 6 days by going through bioconversion to acetophenone accompanying sterically selective oxidation of (R)-1-phenylethanol to obtain 122 mg of (S)-1-phenylethanol at a yield of 61%. Optical purity was obtained at 98% e.e.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06218581B1 |
| Quelldatensatz | uspto-grants-2001_04 |
| ORD ID | ord-6d584782475d4c34bac67076c47702c2 |
| Quellennotiz | uspto-grants-2001_04 |