HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Benzoic Acid → Benzoyl fluoride
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Benzoic Acid | HCID 243 | — |
| Edukt | Diphenylaminosulfur trifluoride | HCID 9859911 | — |
| Lösungsmittel | Dichloromethane | HCID 6344 | — |
| Produkt | Benzoyl fluoride | HCID 67999 | 99,9% |
Reaktionsschritte
A solution of benzoic acid (122 mg, 1 mmol) in CH2Cl2 (5.0 mL) was added to diphenylaminosulfur trifluoride (771 mg, 3.0 mmol ) under N2 and stirred for 16 h at room temperature. After work-up as above benzoyl fluoride (124 mg, quantitative yield) was obtained. The product was identified by g.c.m.s. M+=124
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06222064B1 |
| Quelldatensatz | uspto-grants-2001_04 |
| ORD ID | ord-a908a86135bb47f298ee905e61b0d722 |
| Quellennotiz | uspto-grants-2001_04 |