Quinoline → HCID 20461959, Verbindung

HRID 326046Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 326046
Cl[C:2]1[C:11]([N+:12]([O-:14])=[O:13])=[CH:10][C:9]2[C:4](=[CH:5][CH:6]=[C:7]([Cl:15])[CH:8]=2)[N:3]=1.[OH:16][C:17]1[CH:30]=[CH:29][C:20]([O:21][CH:22]([CH3:28])[C:23]([O:25][CH2:26][CH3:27])=[O:24])=[CH:19][CH:18]=1.N1C2C(=CC=CC=2)C=CC=1>>[Cl:15][C:7]1[CH:8]=[C:9]2[C:4](=[CH:5][CH:6]=1)[N:3]=[C:2]([O:16][C:17]1[CH:18]=[CH:19][C:20]([O:21][CH:22]([CH3:28])[C:23]([O:25][CH2:26][CH3:27])=[O:24])=[CH:29][CH:30]=1)[C:11]([N+:12]([O-:14])=[O:13])=[CH:10]2

Komponenten

4

Edukt 3

HCID 7047Quinoline2×HCID 3017597Propanoic acid, 2-(4-hydroxyphenoxy)-, ethyl esterHCID 13472702HCID 13472702, Verbindung

Produkt 1

HCID 20461959HCID 20461959, Verbindung

Versuchsvorschrift

Ethyl 2-[4-(6-chloro-3-nitroquinolin-2-yloxy)phenoxy]propionate was prepared from 2,6-dichloro-3-nitroquinoline and ethyl 2-(4-hydroxyphenoxy)-propionate following essentially the same procedure as that described in Example 1. Proton magnetic resonance spectrum (CDCl3, δ in ppm): 8.6 (1H, s, C4 quinoline proton); 7.8-7.6 (3H, m, quinoline protons); 7.0 (4H, d of d, phenyl protons); 4.6 (1H, q, CHCH3); 4.2 (2H, q, OCH2CH3); 1.6 (3H, d, CHCH3); 1.2 (3H, t, OCH2CH3).

Quellen und Nachweise

ORD-Eintrag
ord-f4bd92ffd4b64437922b8239dd156f4c
Quelldatensatz
uspto-grants-1984_04
Patentnummer
US04444584

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