HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
6-Hydroxymethylquinoline → 6-Quinolinecarbaldehyde
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 6-Hydroxymethylquinoline | HCID 1514385 | — |
| Katalysator | HCID 178418406 | HCID 178418406 | — |
| Lösungsmittel | Chloroform | HCID 6212 | — |
| Produkt | 6-Quinolinecarbaldehyde | HCID 765653 | 82,7% |
Reaktionsschritte
A mixture of 34 parts of 6-quinolinemethanol, 70 parts of manganese(IV)oxide and 300 parts of trichloromethane was stirred for 24 hours at room temperature. The reaction mixture was filtered over diatomaceous earth and the filtrate was evaporated, yielding 27.7 parts (82.7%) of 6-quinolinecarboxaldehyde; mp. 72° C. (interm. 16).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05268380 |
| Quelldatensatz | uspto-grants-1993_12 |
| ORD ID | ord-f0636ddc50f9408ab8832b5a92269345 |
| Quellennotiz | uspto-grants-1993_12 |