Diisopropyl Ether → Methyl 2-(4-methoxyphenoxy)acetimidate
Reaktionsgleichung
[CH3:1][O:2][C:3]1[CH:12]=[CH:11][C:6]([O:7][CH2:8][C:9]#[N:10])=[CH:5][CH:4]=1.[Na].[CH:14]([O:17]C(C)C)(C)C>CO>[CH3:1][O:2][C:3]1[CH:12]=[CH:11][C:6]([O:7][CH2:8][C:9](=[NH:10])[O:17][CH3:14])=[CH:5][CH:4]=1Komponenten
5
Edukt 3
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
Obtained using the procedure described in section a of Example 16, starting with 27.3 g (0.167 mole) of (4-methoxyphenoxy)acetonitrile [prepared according to K. J. S. Arora et al., J. Chem. Soc. C 1971, 2865] and 0.38 g (0.0167 gram-atom) of sodium in 275 ml of methanol. Reaction time: 24 hours. Yld: 23.9 g (73%), m.p. 95°-96° C. (isopropyl ether).
Aufarbeitung
- customObtained
- customReaction time
- custom24 hours
Quellen und Nachweise
- ORD-Eintrag
- ord-f0c58b17ccf34e3fb19c24870deb7ff8
- Quelldatensatz
- uspto-grants-1993_12
- Patentnummer
- US05270465
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