Methyl 8-methoxycarbonyl-8-methylsulfonyl-12-acetoxyheptadecanoate → HCID 53814061, Verbindung
Reaktionsgleichung
COC([C:5]([S:29]([CH3:32])(=[O:31])=[O:30])([CH2:16][CH2:17][CH2:18][CH:19]([O:25][C:26](=[O:28])[CH3:27])[CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14][CH3:15])=[O:13])=O.COC(C(S(C)(=O)=O)(CC=CC(OC(=O)C)CCCCC)CCCCCCC(OC)=O)=O>>[CH3:32][S:29]([CH:5]([CH2:16][CH:17]=[CH:18][CH:19]([O:25][C:26](=[O:28])[CH3:27])[CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14][CH3:15])=[O:13])(=[O:30])=[O:31]Komponenten
3
Versuchsvorschrift
This compound is prepared by the procedure of Example 3, Step D, except that the methyl 8-methoxycarbonyl-8-methylsulfonyl-12-acetoxyheptadecanoate is replaced by an equivalent quantity of methyl 8-methyoxycarbonyl-8-methylsulfonyl-12-acetoxy-10-heptadecenoate.
Quellen und Nachweise
- ORD-Eintrag
- ord-5d42bb15f63c48a9b67001c8298907fc
- Quelldatensatz
- uspto-grants-1977_04