Dichloromethane → HCID 85556110, Verbindung

Reaktionsgleichung

C([NH:8][CH2:9][CH:10]([CH2:12][S:13][CH:14]([CH3:16])[CH3:15])[OH:11])(OC(C)(C)C)=O.C(Cl)[Cl:18]>>[NH2:8][CH2:9][CH:10]([CH2:12][S:13][CH:14]([CH3:16])[CH3:15])[OH:11].[ClH:18]

Komponenten

Edukt 2

HCID 6344Dichloromethane

HCID 131716253HCID 131716253, Verbindung

Produkt 1

HCID 85556110HCID 85556110, Verbindung

Versuchsvorschrift

BOC-NHCH2CH(OH)CH2SCH(CH3)2 (3.74 g, 0.015 mole) was dissolved in 75 ml CH2Cl2 and occasionally purged with HCl gas over two hours. The solvent was removed in vacuo, and the residue was triturated with Et2O. The solvent was decanted and the residue was stripped to a foam, 2.83 g. IR, NMR, and mass spectral analysis confirmed the structure.

Aufarbeitung

customoccasionally purged with HCl gas over two hours
customThe solvent was removed in vacuo
customthe residue was triturated with Et2O
customThe solvent was decanted

Quellen und Nachweise

ORD-Eintrag: ord-d9dac2abfee148078775f620edc16bb6
Quelldatensatz: uspto-grants-1990_01
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04895834

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