Reaktionsgleichung
[CH2:1](O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15]C.[H][H]>[Ni]>[CH3:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]Komponenten
4
Reagenzien, Katalysatoren, Lösungsmittel 1
Reaktionsbedingungen
- Temperatur
- 240 °C
Versuchsvorschrift
1000 g of 1-hexadecanol (Lorol C 16 from Cognis) were initially charged in a stirrable pressure vessel with 10 g of a nickel catalyst (Ni-5249 P from Engelhard; Ni content=63% by weight) and heated to 240° C. Subsequently, over a period of 12 h, hydrogen was added through a sparging tube at a pressure of 20 bar and the reaction gases were simultaneously discharged through a valve in the reactor lid. Thereafter, the product was cooled, discharged and filtered. This reaction product was fractionated in a distillation to give pure pentadecane and then deodorized with nitrogen. This gives a colorless, liquid and low-odor product.
Aufarbeitung
- customthe reaction gases
- customwere simultaneously discharged through a valve in the reactor lid
- temperatureThereafter, the product was cooled
- filtrationfiltered
- distillationThis reaction product was fractionated in a distillation
Quellen und Nachweise
- ORD-Eintrag
- ord-89a68f16f91846bfbda0598e50707592
- Quelldatensatz
- uspto-grants-2014_11
- Patentnummer
- US08895039B2
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