HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 341723Erstellt: 26. Oktober 2026
Water → Trimethylsilylmethyl methacrylate tertiarybutyl methacrylate
https://huagongshe.com/reaction/341723
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Water | HCID 962 | — |
| Edukt | Azobisisobutyronitrile | HCID 6547 | — |
| Edukt | tert-Butyl methacrylate | HCID 11448 | — |
| Edukt | Methacryloxymethyltrimethylsilane | HCID 2760855 | — |
| Lösungsmittel | Methanol | HCID 887 | — |
| Lösungsmittel | Toluene | HCID 1140 | — |
| Produkt | Trimethylsilylmethyl methacrylate tertiarybutyl methacrylate | HCID 86753511 | 80% |
Reaktionsschritte
Trimethylsilylmethyl methacrylate (TMSMMA) and tertiarybutyl methacrylate (TBMA) were mixed at a ratio of 1:1 so as to prepare a toluene solution having a monomer concentration of 5.0 mol/liter. Next, 2 mol %, on the basis of the monomer, of AIBN was added to the mixture, and the mixture was retained in an oil bath at 80° C. for 15 minutes. Next, the mixture was left standing to cool to room temperature. After the mixture was diluted with toluene, it was dropped into large quantities of a mixed solvent of water and methanol having a mixing ratio of 1:20, and the resulting precipitate was filtered and dried to obtain a base polymer of a resist material. There was thus obtained a trimethylsilylmethyl methacrylate/tertiarybutyl methacrylate copolymer represented by the following formula, ##STR12## wherein each of m and n is a positive integer. In this example, the copolymer described above could be obtained at a yield of 80%, the molecular weight was 38,000 and the dispersion was 1.70.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | US05856071 |
|---|
| Quelldatensatz | uspto-grants-1999_01 |
|---|
| ORD ID | ord-77ca23db37004b9aa1a47099824914fa |
|---|
| Quellennotiz | uspto-grants-1999_01 |
|---|