HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
N-Methylallylamine → (E)-allyl-[4-[4-(6-bromo-benzo[d]isoxazol-3-yl)-phenoxy]-but-2-enyl]-methyl-amine
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | N-Methylallylamine | HCID 69391 | — |
| Edukt | trans-1,4-Dibromo-2-butene | HCID 641245 | — |
| Edukt | (E)-6-bromo-3-[4-(4-bromo-but-2-enyloxy)-phenyl]-benzo[d]isoxazole | HCID 67596916 | — |
| Edukt | 4-(6-Bromo-benzo[d]isoxazol-3-yl)-phenol | HCID 136365325 | — |
| Produkt | (E)-allyl-[4-[4-(6-bromo-benzo[d]isoxazol-3-yl)-phenoxy]-but-2-enyl]-methyl-amine | HCID 67598617 | — |
Reaktionsschritte
Analogously to Example 14d, from 4-(6-bromo-benzo[d]isoxazol-3-yl)-phenol and (E)-1,4-dibromo-2-butene via (E)-6-bromo-3-[4-(4-bromo-but-2-enyloxy)-phenyl]-benzo[d]isoxazole and by reaction with N-allyl-methyl-amine there is obtained (E)-allyl-[4-[4-(6-bromo-benzo[d]isoxazol-3-yl)-phenoxy]-but-2-enyl]-methyl-amine which is converted into the fumarate, MS: m/e 413 (M+H+, 1 Br).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05856503 |
| Quelldatensatz | uspto-grants-1999_01 |
| ORD ID | ord-5875efb8520d4946bac61c8e38102eda |
| Quellennotiz | uspto-grants-1999_01 |