HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Formic Acid → (E)-but-2-enedioic acid;copper
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Formic Acid | HCID 284 | — |
| Edukt | Fumaric Acid | HCID 444972 | — |
| Edukt | Formic acid, copper salt | HCID 44152240 | — |
| Lösungsmittel | Methanol | HCID 887 | — |
| Produkt | (E)-but-2-enedioic acid;copper | HCID 90471545 | 45,7% |
Reaktionsschritte
1.74 g of fumaric acid was dissolved in a mixture solvent having 100 cm3 of methanol and 8 cm3 of formic acid. Then, under stirring at the normal temperature, into the above solution, a further solution in which 3.38 g of formic acid copper was dissolved in 100 cm3 of methanol was dripped. After this solution was left still for one day, the precipitation product was suction-filtered and dried for 120° C./4 hours, whereby 1.23 g of fumaric acid copper was obtained. This substance had the specific surface area of 480 m2 /g.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05862796 |
| Quelldatensatz | uspto-grants-1999_01 |
| ORD ID | ord-aa4934b717674c5d9fe39db460c9e43a |
| Quellennotiz | uspto-grants-1999_01 |