Allyl bromide → N-(2-allyl-3-hydroxy-4-methylphenyl)-3,4,5,6-tetrahydrophthalimide
Reaktionsgleichung
[CH3:1]C1C=CC([N+]([O-])=O)=CC=1O.C(Br)C=C.[CH2:16]([C:19]1[C:24]([OH:25])=[C:23](Cl)[CH:22]=[CH:21][C:20]=1[N:27]1[C:31](=[O:32])[C:30]2[CH2:33][CH2:34][CH2:35][CH2:36][C:29]=2[C:28]1=[O:37])[CH:17]=[CH2:18].ClC1C=CC([N+]([O-])=O)=CC=1O>>[CH2:16]([C:19]1[C:24]([OH:25])=[C:23]([CH3:1])[CH:22]=[CH:21][C:20]=1[N:27]1[C:31](=[O:32])[C:30]2[CH2:33][CH2:34][CH2:35][CH2:36][C:29]=2[C:28]1=[O:37])[CH:17]=[CH2:18]Komponenten
5
Versuchsvorschrift
N-(2-allyl-3-hydroxy-4-methylphenyl)-3,4,5,6-tetrahydrophthalimide (5A) was prepared, as yellow crystals, m.p.: 141°-143° C., from 2-methyl-5-nitrophenol and allyl bromide by the procedures described in Example 3 for preparing 3D from 2-chloro-5-nitrophenol and allyl bromide.